Octadecylamine → HCID 20318442, compound

HRID 1287346Notes

Reaction equation

HRID 1287346 reaction equation
[C:1]([C:5]1[C:6]([OH:19])=[C:7]([CH3:18])[C:8]([CH3:17])=[C:9]([CH2:11][CH2:12][C:13]([O:15]C)=O)[CH:10]=1)([CH3:4])([CH3:3])[CH3:2].[CH2:20]([NH2:38])[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37]>CO>[CH2:20]([NH:38][C:13](=[O:15])[CH2:12][CH2:11][C:9]1[CH:10]=[C:5]([C:1]([CH3:2])([CH3:3])[CH3:4])[C:6]([OH:19])=[C:7]([CH3:18])[C:8]=1[CH3:17])[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37]

Participants

4

Reactant 2

HCID 15793OctadecylamineHCID 20318402HCID 20318402, compound

Product 1

HCID 20318442HCID 20318442, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

A mixture consisting of 10.6 grams of methyl 3-(5-tert.-butyl-2,3-dimethyl-4-hydroxyphenyl)propionate and 11.9 grams of n-octadecylamine were heated together for 1 hour at 160° to 165° and then at 175° to 180° for 4 hours, the methanol of reaction being removed continuously by distillation. Crystallization from methanol yielded white crystals melting at 85° to 87° (Compound 35).

Workup

  1. temperaturewere heated together for 1 hour at 160° to 165°
  2. custombeing removed continuously by distillation
  3. customCrystallization from methanol yielded white crystals melting at 85° to 87° (Compound 35)

Sources & evidence

ORD record
ord-8b0fce33b49044378f705c09d4c3f1af
Source dataset
uspto-grants-1976_10
Patent number
US03984460

Reaction notes

Loading…