Ethyl chloroacetate → HCID 12797321, compound

HRID 1287669Notes

Reaction equation

[Cl:1][C:2]1[CH:18]=[CH:17][C:5]([O:6][C:7]2[CH:8]=[C:9]([CH:13]([CH3:16])[CH:14]=[O:15])[CH:10]=[CH:11][CH:12]=2)=[C:4]([CH3:19])[CH:3]=1.CC[O:22]C(CCl)=O>>[Cl:1][C:2]1[CH:18]=[CH:17][C:5]([O:6][C:7]2[CH:8]=[C:9]([CH:13]([CH3:16])[C:14]([OH:22])=[O:15])[CH:10]=[CH:11][CH:12]=2)=[C:4]([CH3:19])[CH:3]=1

Participants

Reactant 2

HCID 7751Ethyl chloroacetate

HCID 21506157HCID 21506157, compound

Product 1

HCID 12797321HCID 12797321, compound

Procedure

2-[m-(p-chloro-o-methyl-phenoxy)phenyl]propionaldehyde, which has been synthesized in accordance with Example 1 from 3-(p-chloro-o-methyl-phenoxyphenyl)acetophenone having the melting point of 148° - 156° C./0.5 mmHg and ethyl ester of chloroacetic acid, is subjected to oxidative treatment in the manner of Example 1 to obtain the contemplated product.

Workup

customto obtain the contemplated product

Sources & evidence

ORD record: ord-314f1747b8b748a19f1a2e5f4b7eff43
Source dataset: uspto-grants-1976_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03985779

Reaction notes

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