HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,2-Dimethoxyethane → HCID 21506588, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,2-Dimethoxyethane | HCID 8071 | — |
| Reactant | Ethyl chloroformate | HCID 10928 | — |
| Reactant | Sodium hydride | HCID 24758 | — |
| Reactant | (1H-Perimidin-2-yl)methanol | HCID 14067730 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 21506588 | HCID 21506588 | — |
Reaction Steps
Equivalent quantities of 2-perimidinemethanol and sodium hydride are heated for 1/2 hour in dimethoxyethane. After the evolution of hydrogen has stopped, ethyl chloroformate is added to the solution, and the resulting mixture is stirred for 3 hours, poured into water and the separated solid collected and recrystallized twice from dimethoxyethane to give the desired product, 1H, 3H-oxazolo[3,4-a]perimidine-3-one, m.p. 194°-195°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03985880 |
| Source dataset | uspto-grants-1976_10 |
| ORD ID | ord-d29c1c6e5ac542818aac50734cf0e456 |
| Source note | uspto-grants-1976_10 |