HuagongsheHuagongshe Chemistry Print Report · For research reference only
Thionyl Chloride → 11-Chloro-6,11-dihydrodibenz[b,e]thiepin
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Thionyl Chloride | HCID 24386 | — |
| Reactant | 6,11-Dihydrodibenzo[b,e]thiepin-11-ol | HCID 601431 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | 11-Chloro-6,11-dihydrodibenz[b,e]thiepin | HCID 12514557 | — |
Reaction Steps
19.5 G. of 6,11-dihydro-dibenzo[b,e]thiepin-11-ol, 25 ml. of thionyl chloride and 180 ml. of absolute benzene are heated under reflux conditions for 2 hours. The mixture is evaporated, treated several times with absolute benzene and then evaporated. The crude 11-chloro-6,11-dihydro-dibenzo[b,e]thiepin obtained as the residue is used without further purification.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03985895 |
| Source dataset | uspto-grants-1976_10 |
| ORD ID | ord-b0601f57b40a45108f4dae91f40ef2b3 |
| Source note | uspto-grants-1976_10 |