HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triphenylphosphine → HCID 67808197, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | ethyl N-ethoxycarbonyliminocarbamate | HCID 220568 | — |
| Reactant | HCID 5369482 | HCID 5369482 | — |
| Reactant | HCID 19375135 | HCID 19375135 | — |
| Product | HCID 67808197 | HCID 67808197 | 85% |
Reaction Steps
By the method of example 13, 4-((2,2-dimethoxyethyl)thio)phenol (example 64) and (E)-2-methyl-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-butenol (Chem. Abstr., 94, 65904 h) are coupled in the presence of triphenylphosphine and diethyl azodicarboxylate to provide (E)-1-((2,2-dimethoxyethyl)thio)-4-(2-methyl-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-butenyloxy)benzene as a colorless oil after chromatography (85% yield).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05464865 |
| Source dataset | uspto-grants-1995_11 |
| ORD ID | ord-1457c05be8454f30ac7b9e2c036b7afb |
| Source note | uspto-grants-1995_11 |