Methyl iodide → HCID 21502526, compound

HRID 1288511Notes

Reaction equation

HRID 1288511 reaction equation
[CH3:1][CH:2]([N:14]([CH3:16])[CH3:15])[CH2:3][CH2:4][CH:5]1[C:10]([CH3:12])([CH3:11])[CH2:9][CH2:8][CH2:7][CH:6]1[CH3:13].[CH3:17][I:18]>C1C=CC=CC=1>[I-:18].[CH3:1][CH:2]([N+:14]([CH3:17])([CH3:15])[CH3:16])[CH2:3][CH2:4][CH:5]1[C:10]([CH3:11])([CH3:12])[CH2:9][CH2:8][CH2:7][CH:6]1[CH3:13]

Participants

4

Reactant 2

HCID 6328Methyl iodideHCID 21502500HCID 21502500, compound

Product 1

HCID 21502526HCID 21502526, compoundYield 90%

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

To a solution of [1-methyl-3-(2,6,6-trimethylcyclohexyl)propyl]dimethylamine (3.0 g) in benzene (20 cc) was added methyliodide (10.0 g), and the mixture was allowed to stand over night. Precipitated crystals were gathered by filtration, and recrystallized from a mixed solvent of benzene and ether to give colorless crystals (4.4 g) of [1-methyl-3-(2,6,6-trimethylcyclohexyl)propyl]trimethylammonium iodide.

Workup

  1. waitto stand over night
  2. customPrecipitated crystals
  3. filtrationwere gathered by filtration
  4. customrecrystallized from a mixed solvent of benzene and ether

Sources & evidence

ORD record
ord-481f1fba7554465682489ad2f18ced84
Source dataset
uspto-grants-1976_10
Patent number
US03988373

Reaction notes

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