[1-Methyl-3-(2,6,6-trimethyl-2-cyclohexenyl)-2(trans)-propenyl]dimethyl(4-chlorobenzyl)ammonium iodide → [1-Methyl-3-(2,6,6-trimethyl-2-cyclohexenyl)-2(trans)-propenyl]dimethyl(4-chlorobenzyl)ammonium chloride

HRID 1288519ノート

反応式

HRID 1288519 の反応式
[I-].[CH3:2][CH:3]([N+:15]([CH3:25])([CH3:24])[CH2:16][C:17]1[CH:22]=[CH:21][C:20]([Cl:23])=[CH:19][CH:18]=1)/[CH:4]=[CH:5]/[CH:6]1[C:11]([CH3:13])([CH3:12])[CH2:10][CH2:9][CH:8]=[C:7]1[CH3:14]>[Ag]Cl.CO>[Cl-:23].[CH3:2][CH:3]([N+:15]([CH3:25])([CH3:24])[CH2:16][C:17]1[CH:18]=[CH:19][C:20]([Cl:23])=[CH:21][CH:22]=1)/[CH:4]=[CH:5]/[CH:6]1[C:11]([CH3:13])([CH3:12])[CH2:10][CH2:9][CH:8]=[C:7]1[CH3:14]

参加物

4

反応物 1

HCID 21502450[1-Methyl-3-(2,6,6-trimethyl-2-cyclohexenyl)-2(trans)-propenyl]dimethyl(4-chlorobenzyl)ammonium iodide

生成物 1

HCID 21502481[1-Methyl-3-(2,6,6-trimethyl-2-cyclohexenyl)-2(trans)-propenyl]dimethyl(4-chlorobenzyl)ammonium chloride収率 111.5%

試薬・触媒・溶媒 2

HCID 24561Silver Chloride触媒HCID 887Methanol溶媒

実験手順

A mixture of [1-methyl-3-(2,6,6-trimethyl-2-cyclohexenyl)-2(trans)-propenyl]dimethyl(4-chlorobenzyl)ammonium iodide (2.0 g), silver chloride (1.0 g) and absolute methanol (50 cc) was refluxed for 2 hours, and the reaction mixture was filtered. The solvent of the filtrate was distilled off to give hygroscopic colorless crystals (0.9 g) of [1-methyl-3-(2,6,6-trimethyl-2-cyclohexenyl)-2(trans)-propenyl]dimethyl(4-chlorobenzyl)ammonium chloride.

後処理

  1. temperaturewas refluxed for 2 hours
  2. filtrationthe reaction mixture was filtered
  3. distillationThe solvent of the filtrate was distilled off

出典と根拠

ORDレコード
ord-ab552f525aed427d99a40a348038bef3
出典データセット
uspto-grants-1976_10
特許番号
US03988373

反応ノート

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