Methyl iodide → HCID 21502468, compound

HRID 1288524Notes

Reaction equation

HRID 1288524 reaction equation
[CH3:1][C:2]1([CH3:14])[CH2:7][CH:6]([CH3:8])[CH2:5][CH:4]([CH2:9][CH2:10][N:11]([CH3:13])[CH3:12])[CH2:3]1.[CH3:15][I:16]>C1C=CC=CC=1>[I-:16].[CH3:14][C:2]1([CH3:1])[CH2:7][CH:6]([CH3:8])[CH2:5][CH:4]([CH2:9][CH2:10][N+:11]([CH3:15])([CH3:12])[CH3:13])[CH2:3]1

Participants

4

Reactant 2

HCID 6328Methyl iodideHCID 21502532HCID 21502532, compound

Product 1

HCID 21502468HCID 21502468, compoundYield 93.1%

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

To a solution of [2-(3,3,5-trimethylcyclohexyl)ethyl]dimethylamine (1.0 g) in benzene (30 cc) was added methyliodide (2.0 g), and the mixture was allowed to stand over night. Precipitated crystals were gathered by filtration and recrystallized from a mixed solvent of benzene and ether to give colorless crystals (1.6 g) of [2-(3,3,5-trimethylcyclohexyl)ethyl]trimethylammonium iodide, m.p. 263°-265° C.

Workup

  1. waitto stand over night
  2. customPrecipitated crystals
  3. filtrationwere gathered by filtration
  4. customrecrystallized from a mixed solvent of benzene and ether

Sources & evidence

ORD record
ord-5d31392d59904a13ba14034482755e34
Source dataset
uspto-grants-1976_10
Patent number
US03988373

Reaction notes

Loading…