HCID 18925402, compound → HCID 18925389, compound

HRID 1289081Notes

Reaction equation

HRID 1289081 reaction equation
[N+](C1C=CSC=1C1C=CC(Cl)=CC=1)([O-])=O.[N+:16]([C:19]1[CH:23]=[CH:22][S:21][C:20]=1[C:24]1[CH:29]=[CH:28][CH:27]=[C:26]([Cl:30])[CH:25]=1)([O-])=O>>[NH2:16][C:19]1[CH:23]=[CH:22][S:21][C:20]=1[C:24]1[CH:29]=[CH:28][CH:27]=[C:26]([Cl:30])[CH:25]=1

Participants

3

Reactant 2

HCID 18925402HCID 18925402, compoundHCID 18925418HCID 18925418, compound

Product 1

HCID 18925389HCID 18925389, compoundYield 71%

Procedure

The same procedures as described in Example 3 were carried out except that 3-nitro-2-(4-chlorophenyl)thiophene was replaced by 3-nitro-2-(3-chlorophenyl)thiophene. The yield was 71%. 1 H-NMR(CDCl3, δ value):3.84(2H, brs), 6.65(1H, d, J=5.1), 7.14(1H, d, J=5.1), 7.21(1H, dd, J=1.5, 8.8), 7.35(1H, dt, J=1.5, 8.8), 7.41(1H, dd, J=1.5, 8.8), 7.51-7.53(1H, m)

Sources & evidence

ORD record
ord-4342522384504c019368c4798e056440
Source dataset
uspto-grants-1998_05
Patent number
US05747518

Reaction notes

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