Sodium Acetate → HCID 86752515, compound

HRID 1289170Notes

Reaction equation

HRID 1289170 reaction equation
[CH2:1]([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1[CH2:14][O:15][C:16]1[CH:23]=[CH:22][C:19]([CH:20]=O)=[CH:18][CH:17]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C([O-])(=O)C.[Na+].[S:29]1[CH2:35][C:33](=[O:34])[NH:32][C:30]1=[S:31]>C(O)(=O)C>[CH2:1]([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1[CH2:14][O:15][C:16]1[CH:17]=[CH:18][C:19]([CH:20]=[C:35]2[S:29][C:30](=[S:31])[NH:32][C:33]2=[O:34])=[CH:22][CH:23]=1)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

5

Reactant 3

HCID 517045Sodium AcetateHCID 1201546RhodanineHCID 21191272HCID 21191272, compound

Product 1

HCID 86752515HCID 86752515, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

Under a nitrogen atmosphere in a round bottom flask 4-[(2-benzylphenyl)methoxy]benzaldehyde (4.5 g, 14.9 mmol), sodium acetate (4.27 g, 52 mmol), and rhodanine (1.98 g, 14.9 mmol) were dissolved in 75 ml of acetic acid. The reaction solution was then heated to reflux and maintained at this temperature for about three days.

Workup

  1. temperatureThe reaction solution was then heated
  2. temperatureto reflux
  3. temperaturemaintained at this temperature for about three days

Sources & evidence

ORD record
ord-355e2fda183e44f59de981fb3c6afee3
Source dataset
uspto-grants-1998_05
Patent number
US05747517

Reaction notes

Loading…