HuagongsheHuagongshe Chemistry Print Report · For research reference only
Maleimide → 3a,4,7,7a-Tetrahydro-4-methoxy-4,7-ethano-1H-isoindole-1,3(2H)-dione
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Maleimide | HCID 10935 | — |
| Reactant | 1-Methoxycyclohexa-1,4-diene | HCID 76156 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | 3a,4,7,7a-Tetrahydro-4-methoxy-4,7-ethano-1H-isoindole-1,3(2H)-dione | HCID 15289153 | — |
Reaction Steps
11 g (0.1 mol) of 1-methoxycyclohexa-1,4-diene are heated under reflux with 0.1 g of tris(triphenylphosphine)-ruthenium dichloride and 8.8 g (0.09 mol) of maleimide in 100 ml of absolute chloroform overnight. The mixture is concentrated and the residue is recrystallized from 100 ml of toluene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05753669 |
| Source dataset | uspto-grants-1998_05 |
| ORD ID | ord-1437bdb0047944af88b30d6a77d03725 |
| Source note | uspto-grants-1998_05 |