3-Oxetanemethanol, 3-(1,1-dimethylethyl)- → 4-t-Butyl-1-[2-(prop-2-ynylthio)ethyl]-2,6,7-trioxabicyclo[2.2.2]octane

HRID 129288Notes

Reaction equation

HRID 129288 reaction equation
[CH2:1]([S:4][CH2:5][CH2:6][C:7]([OH:9])=[O:8])[C:2]#[CH:3].[C:10]([C:14]1([CH2:18]O)[CH2:17][O:16][CH2:15]1)([CH3:13])([CH3:12])[CH3:11]>>[C:10]([C:14]12[CH2:15][O:16][C:7]([CH2:6][CH2:5][S:4][CH2:1][C:2]#[CH:3])([O:9][CH2:18]1)[O:8][CH2:17]2)([CH3:13])([CH3:12])[CH3:11]

Participants

3

Reactant 2

HCID 1807403-Oxetanemethanol, 3-(1,1-dimethylethyl)-HCID 193733763-(Prop-2-ynylthio)propionic acid

Product 1

HCID 193732994-t-Butyl-1-[2-(prop-2-ynylthio)ethyl]-2,6,7-trioxabicyclo[2.2.2]octane

Procedure

4-t-Butyl-1-[2-(prop-2-ynylthio)ethyl]-2,6,7-trioxabicyclo[2.2.2]octane was prepared from 3-(prop-2-ynylthio)propionic acid and 3-t-butyl-3- hydroxymethyloxetane using methodology described in Example I.

Sources & evidence

ORD record
ord-c86e8a0122ad4297916ce3e254939d42
Source dataset
uspto-grants-1995_11
Patent number
US05466710

Reaction notes

Loading…