3-Oxetanemethanol, 3-(1,1-dimethylethyl)- → 4-t-Butyl-1-(but-3-ynyloxymethyl)-2,6,7-trioxabicyclo[2.2.2]octane

HRID 129294Notes

Reaction equation

HRID 129294 reaction equation
[CH2:1]([O:5][CH2:6][C:7]([OH:9])=[O:8])[CH2:2][C:3]#[CH:4].[C:10]([C:14]1([CH2:18]O)[CH2:17][O:16][CH2:15]1)([CH3:13])([CH3:12])[CH3:11]>>[C:10]([C:14]12[CH2:15][O:16][C:7]([CH2:6][O:5][CH2:1][CH2:2][C:3]#[CH:4])([O:9][CH2:18]1)[O:8][CH2:17]2)([CH3:13])([CH3:12])[CH3:11]

Participants

3

Reactant 2

HCID 1807403-Oxetanemethanol, 3-(1,1-dimethylethyl)-HCID 193733742-(But-3-yn-1-yloxy)acetic acid

Product 1

HCID 193734194-t-Butyl-1-(but-3-ynyloxymethyl)-2,6,7-trioxabicyclo[2.2.2]octane

Procedure

4-t-Butyl-1-(but-3-ynyloxymethyl)-2,6,7-trioxabicyclo[2.2.2]octane was prepared from 2-(but-3-ynyloxy)acetic acid and 3-t-butyl-3-hydroxymethyloxetane using methodology described in Example I

Sources & evidence

ORD record
ord-f3747124ee4a48ba866fd451816cd07e
Source dataset
uspto-grants-1995_11
Patent number
US05466710

Reaction notes

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