3-Oxetanemethanol, 3-(1,1-dimethylethyl)- → 4-t-Butyl-1-(hept-6-ynyl)-2,6,7-trioxabicyclo[2.2.2]octane

HRID 129297Notes

Reaction equation

HRID 129297 reaction equation
[C:1]([OH:10])(=[O:9])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][C:7]#[CH:8].[C:11]([C:15]1([CH2:19]O)[CH2:18][O:17][CH2:16]1)([CH3:14])([CH3:13])[CH3:12]>>[C:11]([C:15]12[CH2:16][O:17][C:1]([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][C:7]#[CH:8])([O:10][CH2:19]1)[O:9][CH2:18]2)([CH3:14])([CH3:13])[CH3:12]

Participants

3

Reactant 2

HCID 1807403-Oxetanemethanol, 3-(1,1-dimethylethyl)-HCID 53127007-Octynoic acid

Product 1

HCID 193733594-t-Butyl-1-(hept-6-ynyl)-2,6,7-trioxabicyclo[2.2.2]octane

Procedure

4-t-Butyl-1-(hept-6-ynyl)-2,6,7-trioxabicyclo[2.2.2]octane was prepared from oct-7-ynoic acid and 3-t-butyl-3-hydroxymethyloxetane using methodology described in Example I.

Sources & evidence

ORD record
ord-16f59f75f2ad41c0803c2facab9dcac4
Source dataset
uspto-grants-1995_11
Patent number
US05466710

Reaction notes

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