2-Propyl-2-oxetanemethanol → 1-(Hept-6-ynyl)-4-n-propyl-2,6,7-trioxabicyclo[2.2.2]octane

HRID 129298Notes

Reaction equation

HRID 129298 reaction equation
[C:1]([OH:10])(=[O:9])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][C:7]#[CH:8].[OH:11][CH2:12][C:13]1([CH2:17][CH2:18][CH3:19])[CH2:16]O[CH2:14]1>>[CH2:2]([C:1]12[O:11][CH2:12][C:13]([CH2:17][CH2:18][CH3:19])([CH2:16][O:10]1)[CH2:14][O:9]2)[CH2:3][CH2:4][CH2:5][CH2:6][C:7]#[CH:8]

Participants

3

Reactant 2

HCID 1838902-Propyl-2-oxetanemethanolHCID 53127007-Octynoic acid

Product 1

HCID 193734141-(Hept-6-ynyl)-4-n-propyl-2,6,7-trioxabicyclo[2.2.2]octane

Procedure

1-(Hept-6-ynyl)-4-n-propyl-2,6,7-trioxabicyclo[2.2.2]octane was prepared from oct-7-ynoic acid and 3-hydroxymethyl-3-n-propyloxetane using methodology described in Example I.

Sources & evidence

ORD record
ord-611007065a0c4dfaafa059688329e71d
Source dataset
uspto-grants-1995_11
Patent number
US05466710

Reaction notes

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