HuagongsheHuagongshe Chemistry Print Report · For research reference only
Cyclopenta-2,4-dien-1-amine;cyclopenta-1,3-diene;iron(2+) → HCID 178463282, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Cyclopenta-2,4-dien-1-amine;cyclopenta-1,3-diene;iron(2+) | HCID 15501615 | — |
| Reactant | 1-{6-[(1E)-N-(2,4,6-Trimethylphenyl)ethanimidoyl]pyridin-2-yl}ethan-1-one | HCID 22134468 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 178463282 | HCID 178463282 | — |
Reaction Steps
Monoimine 2-[1-(2,4,6-trimethylphenylimino)ethyl]-6-acetylpyridine (1, 263 mg, 0.94 mmol ) and ferrocenylamine (280 mg, 1.03 mmol) were dissolved in 40 ml of toluene. To this solution, molecular sieves (4 Å) were added. After standing for 16 hours the mixture was filtered. The solvent was removed in vacuo. The residue was recrystallised from ethanol. Yield 180 mg (41%) of mixed diimine 21.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07238764B2 |
| Source dataset | uspto-grants-2007_07 |
| ORD ID | ord-e04631877dfc4020ad15f6ef63d20865 |
| Source note | uspto-grants-2007_07 |