Cyclohexene → HCID 136358443, compound

HRID 1294957Notes

Reaction equation

HRID 1294957 reaction equation
[CH2:1]([N:4]1[C:12]2[C:7](=[CH:8][CH:9]=[CH:10][C:11]=2[CH3:13])[C:6]([C:14]2[CH:19]=[CH:18][C:17]([O:20]C)=[CH:16][CH:15]=2)=[N:5]1)[CH:2]=[CH2:3].B(Br)(Br)Br.C1CCCCC=1>>[CH2:1]([N:4]1[C:12]2[C:7](=[CH:8][CH:9]=[CH:10][C:11]=2[CH3:13])[C:6]([C:14]2[CH:15]=[CH:16][C:17]([OH:20])=[CH:18][CH:19]=2)=[N:5]1)[CH:2]=[CH2:3]

Participants

4

Reactant 3

HCID 8079CyclohexeneHCID 25134Boron tribromideHCID 68884899HCID 68884899, compound

Product 1

HCID 136358443HCID 136358443, compoundYield 32.9%

Procedure

Prepared according to Method D step C from 1-allyl-3-(4-methoxyphenyl)-7-methyl-1H-indazole (0.027 g, 0.23 mmol), boron tribromide (0.10 mL, 1.05 mmol) and 0.3 mL of cyclohexene to give the product (0.020 g) as a tan solid.

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-9ca11875c0634b7f9c15c51a7f8ce7c4
Source dataset
uspto-grants-2007_07
Patent number
US07241791B2

Reaction notes

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