Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Oxygen | HCID 977 | — |
| Reactant | adamantane-1,3,5-tricarboxylic acid | HCID 754344 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | HCID 10039509 | HCID 10039509 | 70% |
Reaction Steps
In an atmosphere of oxygen, to 25 mL of acetic acid was added 10 mmole of the 1,3,5-tricarboxyadamantane, 1 mmole of NHPI and 0.005 mmole of Co(AA)2 and the mixture was stirred for 6 hours at 75° C. As a result, the conversion was 76% and 1,3,5-tricarboxy-7-adamantanol was obtained in a 70% yield.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | USRE039744E1 |
|---|
| Source dataset | uspto-grants-2007_07 |
|---|
| ORD ID | ord-a1c7d35355e340d9bbd5a35cd0a1af5a |
|---|
| Source note | uspto-grants-2007_07 |
|---|
