Allyl 4-Hydroxybenzoate → HCID 19372209, compound

HRID 129669Notes

Reaction equation

HRID 129669 reaction equation
[C:1]12([C:11]3[CH:12]=[C:13]([CH:17]=[CH:18][CH:19]=3)[C:14](Cl)=[O:15])[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[CH2:2]1)[CH2:8]2.[OH:20][C:21]1[CH:32]=[CH:31][C:24]([C:25]([O:27][CH2:28][CH:29]=[CH2:30])=[O:26])=[CH:23][CH:22]=1>>[C:1]12([C:11]3[CH:12]=[C:13]([CH:17]=[CH:18][CH:19]=3)[C:14]([O:20][C:21]3[CH:22]=[CH:23][C:24]([C:25]([O:27][CH2:28][CH:29]=[CH2:30])=[O:26])=[CH:31][CH:32]=3)=[O:15])[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[CH2:2]1)[CH2:8]2

Participants

3

Reactant 2

HCID 11171300Allyl 4-HydroxybenzoateHCID 15052594HCID 15052594, compound

Product 1

HCID 19372209HCID 19372209, compoundYield 68%

Procedure

In a manner analogous to Example 9(a) by reacting 1.5 g (5.5 mmoles) of 3-(1-adamantyl)benzoyl chloride with 980 mg (5.5 mmoles) of allyl 4-hydroxybenzoate, 1.5 g (68% yield) of the expected ester in the form of a colorless oil are obtained.

Sources & evidence

ORD record
ord-71430d0fe900457db2ec8ac27ba433b4
Source dataset
uspto-grants-1995_11
Patent number
US05468897

Reaction notes

Loading…