Allyl 4-Hydroxybenzoate → HCID 14852503, compound

HRID 129672Notes

Reaction equation

HRID 129672 reaction equation
[C:1]12([C:11]3[CH:12]=[C:13]([CH:17]=[CH:18][C:19]=3[CH2:20][CH3:21])[C:14](Cl)=[O:15])[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[CH2:2]1)[CH2:8]2.[OH:22][C:23]1[CH:34]=[CH:33][C:26]([C:27]([O:29][CH2:30][CH:31]=[CH2:32])=[O:28])=[CH:25][CH:24]=1>>[C:1]12([C:11]3[CH:12]=[C:13]([CH:17]=[CH:18][C:19]=3[CH2:20][CH3:21])[C:14]([O:22][C:23]3[CH:24]=[CH:25][C:26]([C:27]([O:29][CH2:30][CH:31]=[CH2:32])=[O:28])=[CH:33][CH:34]=3)=[O:15])[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[CH2:2]1)[CH2:8]2

Participants

3

Reactant 2

HCID 11171300Allyl 4-HydroxybenzoateHCID 19372191HCID 19372191, compound

Product 1

HCID 14852503HCID 14852503, compoundYield 71%

Procedure

In a manner analogous to Example 9(e), by reacting 2.35 g (8.1 mmoles) of 3-(1-adamantyl)-4-ethylbenzoyl chloride with 1.44 g (8.1 mmoles) of allyl 4-hydroxybenzoate, 2.54 g (71% yield) of the expected ester having a melting point of 111°-113° C. are obtained.

Sources & evidence

ORD record
ord-73a45905f35a488583f6b4c86790bbeb
Source dataset
uspto-grants-1995_11
Patent number
US05468897

Reaction notes

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