Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Benzoyl chloride | HCID 7412 | — |
| Reactant | Dimethyl Carbonate | HCID 12021 | — |
| Reactant | Trifluoromethanesulfonic acid | HCID 62406 | — |
| Product | Methyl triflate | HCID 9526 | 96.8% |
Reaction Steps
A further 49.15 g (0.328 mol) of trifluoromethanesulfonic acid, 46.10 g (0.328 mol) of benzoyl chloride and 29.49 g (0.328 mol) of dimethyl carbonate are added to the distillation residue with stirring. The reaction mixture is subsequently heated at 90° C. using an oil bath (temperature in the oil bath) for 6 hours, giving 52.00 g (yield: 96.8%) of pure methyl triflate by distillation.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US07247740B2 |
|---|
| Source dataset | uspto-grants-2007_07 |
|---|
| ORD ID | ord-a6b5714b85f84a208778a2f29791f79c |
|---|
| Source note | uspto-grants-2007_07 |
|---|
