化工社化工社 化学情報印刷レポート · 研究参考用
Triethyl phosphite → Diethyl (Methoxymethyl)phosphonate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Triethyl phosphite | HCID 31215 | — |
| 反応物 | Bromomethyl methyl ether | HCID 83093 | — |
| 生成物 | Diethyl (Methoxymethyl)phosphonate | HCID 11658394 | 98% |
反応手順
To a sample of 17.90 mL (0.104 mol) of triethylphosphite at -78° C. under argon was added dropwise 8.50 mL (0.104 mol) of bromomethyl methyl ether. The mixture slowly warmed to RT and stirred for 24 h, when it was fractionally distilled (bp 100° C., 5 mm) to provide 16.22 g (98%) of title compound as a pale yellow oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05470845 |
| 出典データセット | uspto-grants-1995_11 |
| ORD ID | ord-b9f3818a0f834bd892592a8c40680371 |
| 出典メモ | uspto-grants-1995_11 |