Hydrazine hydrate (1:1) → HCID 86597181, compound

Participants

Reaction Conditions

Reaction Steps

The hydrazine hydrate (7.12 mL; 147 mmol) is dissolved in 220 mL of ethanol. This solution is stirred at 0° C. and 3,4-dichlorobenzenisothiocyanate (20.00 g; 98 mmol) is added dropwise, and the reaction mixture is warmed to RT and stirred for two hours. After being cooled to 0° C., the mixture is filtered and the solid washed by cold ethanol (40 mL). The solid is crystallized from ethanol to yield ([(3,4-dichlorophenyl)-amino]hydrazinomethane-1-thione) (12.702 g; 55%) as a white solid.

Provenance & Evidence