Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
(5,6-Dichloropyridin-3-yl)methanol → 5,6-Dichloropyridine-3-carbaldehyde
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | (5,6-Dichloropyridin-3-yl)methanol | HCID 21882961 | — |
| 촉매 | HCID 178418406 | HCID 178418406 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | 5,6-Dichloropyridine-3-carbaldehyde | HCID 11535654 | 48% |
반응 단계
Combine (5,6-dichloro-pyridin-3-yl)-methanol (3.05 g, 17.11 mmol) and manganese dioxide (37.2 g, 427.9 mmol) in CH2Cl2 (25 mL). Stir the reaction mixture at rt overnight. Filter the reaction mixture through Celite® washing with CH2Cl2 (2×10 mL). Concentrate the filtrate and dry under vacuum to provide the title compound (1.44 g, 48%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07381719B2 |
| 출처 데이터셋 | uspto-grants-2008_06 |
| ORD ID | ord-1eedb8e0688043248b814c4e9ca0649d |
| 출처 메모 | uspto-grants-2008_06 |