HuagongsheHuagongshe Chemistry Print Report · For research reference only
Formic Acid → 1,2-Dodecanediol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Formic Acid | HCID 284 | — |
| Reactant | Hydrogen Peroxide | HCID 784 | — |
| Reactant | 1-Dodecene | HCID 8183 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 1,2-Dodecanediol | HCID 92866 | — |
Reaction Steps
336 g (2.00 mol) of 1-dodecene were reacted with 236 g of formic acid and 185 g of a 50% strength aqueous H2O2 solution in accordance with Example 4. 412 g of ethanol were employed for the Marlon AS3 acid-catalyzed transesterification, and the main fraction obtained after the workup by distillation was 99.5% pure, virtually odorless 1,2-dodecanediol.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07385092B2 |
| Source dataset | uspto-grants-2008_06 |
| ORD ID | ord-e3f2b7809e3f48e28f4d2541ab2247dc |
| Source note | uspto-grants-2008_06 |