Pyridine → HCID 69200236, compound

Participants

Reaction Steps

6.05 grams (0.025 mol) of ethyl 1-n-hexyl-2-hydroxy-cyclopentane carboxylate obtained in Example 17 were diluted with 60 ml of methylene chloride. At room temperature and with magnetic stirring, 3.05 ml (0.0375 mol) of pyridine was slowly added, then 4.99 ml of 3-methyl-benzoyl chloride was dropwise added. Then the procedure as described in Example 23 was followed, to give 10.01 g of brown liquid. MS: m/e 361(M++1), 360(M+′), 315(M+—OCH2CH3), 287(M+—CO2CH2CH3), 276, 241(M+—CH3C6H4CO), 225(M+—CH3C6H4CO2), 195, 151, 140, 119(base), 118, 91, 77.

Provenance & Evidence