HRID134254

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID8058

n-Hexane

C6H14

HCID11776

Triphenylphosphine

C18H15P

HCID12369

1-Bromoheptane

C7H15Br

结构：CCCCCCC[P+](c1ccccc1)(c1ccccc1)c1ccccc1

HCID2724568

未命名化合物

HCID11137279

ethyl 5-oxopentanoate

C7H12O3

HCID178418339

Butyllithium

C4H9Li

PRODUCTS

生成物

HCID2778034

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-be9e6d12d73c48ad98cf1d96bd084644
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (9/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (9/10)

反应 SMILES

[Br-:1].[Br:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH3:35].[CH2:2]([CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])[P+:9]([c:10]1[cH:11][cH:12][cH:13][cH:14][cH:15]1)([c:16]1[cH:17][cH:18][cH:19][cH:20][cH:21]1)[c:22]1[cH:23][cH:24][cH:25][cH:26][cH:27]1.[CH3:70][CH2:71][CH2:72][CH2:73][CH2:74][CH3:75].[Li:55][CH2:56][CH2:57][CH2:58][CH3:59].[O:60]=[CH:61][CH2:62][CH2:63][CH2:64][C:65](=[O:66])[O:67][CH2:68][CH3:69].[c:36]1([P:37]([c:38]2[cH:39][cH:40][cH:41][cH:42][cH:43]2)[c:44]2[cH:45][cH:46][cH:47][cH:48][cH:49]2)[cH:50][cH:51][cH:52][cH:53][cH:54]1>>[CH:2]([CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])=[CH:61][CH2:62][CH2:63][CH2:64][C:65](=[O:66])[O:67][CH2:68][CH3:69]