[(4-Nitrophenyl)ethyl]benzylamine → [(4-Aminophenyl)ethyl]benzylamine

HRID 13483Notes

Reaction equation

HRID 13483 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([CH2:10][CH2:11][NH:12][CH2:13][C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)=[CH:6][CH:5]=1)([O-])=O>CO.[Pd]>[NH2:1][C:4]1[CH:5]=[CH:6][C:7]([CH2:10][CH2:11][NH:12][CH2:13][C:14]2[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=2)=[CH:8][CH:9]=1

Participants

4

Reactant 1

HCID 10999672[(4-Nitrophenyl)ethyl]benzylamine

Product 1

HCID 54424736[(4-Aminophenyl)ethyl]benzylamine

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 887MethanolSolvent

Procedure

The mixture containing [(4-nitrophenyl)ethyl]benzylamine in methanol with catalytic amount of 10% Pd/C was hydrogenated until disappearance of yellow color to yield [(4-aminophenyl)ethyl]benzylamine. MS: MH+=226.

Sources & evidence

ORD record
ord-823a64c70ed947ebae617a53f5cb09a6
Source dataset
uspto-grants-2010_06
Patent number
US07728010B2

Reaction notes

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