Triethylamine → HCID 21095787, compound

Participants

Reaction Steps

To 9.61 g (0.049 mol) of 2-bromo-1H-indene and 1.13 g (0.98 mmol) of Pd(PPh3)4 in 25 ml of toluene, 7.5 ml (5.45 g, 0.054 mol) of Et3N and 4.88 g (0.054 mol) of tBuPH2 were added. This mixture was refluxed for 14 hours, cooled to room temperature, and filtered through glass frit (G3) to separate out compound 15. The filtrate was evaporated to dryness. The crude product was distilled in vacuum (108–110° C./3 mm). Yield 3.07 g (31%) of crystalline solid of 14.

Provenance & Evidence