Triethylamine → HCID 21095788, compound

Participants

Reaction Steps

To 15.61 g (0.080 mol) of 2-bromo-1H-indene and 1.38 g (1.19 mmol) of Pd(PPh3)4 in 60 ml of toluene, 22.3 ml (16.19 g, 0.160 mol) of Et3N and 3.60 g (0.040 mol) of tBuPH2 were added. This mixture was refluxed for 24 hours, cooled to room temperature, and passed through short column with Silica Gel using 200 ml of toluene as eluent. The filtrate was evaporated to dryness to give oil, which after treatment with 150 ml of hot ethanol gave a gray precipitate. This precipitate was separated (G3), washed with 3×5 ml of cold ethanol and dried in vacuum. Yield 10.83 g (85%) of 15.

Provenance & Evidence