Triethylamine → HCID 17817753, compound

Participants

Reaction Steps

To 4.00 g (0.021 mol) of 2-bromo-1-indene and 0.46 g (0.40 mmol) of Pd(PPh3)4 in 20 ml of toluene, 3.2 ml (2.32 g, 0.023 mol) of Et3N and, then, 4.52 g (0.020 mol) of 17 were added. This mixture was refluxed for 13 hours, cooled to room temperature, and passed through short column with Silica Gel using 150 ml of toluene as eluent. The resulted solution was evaporated to dryness. The crude product was crystallized from ethanol. Yield 1.63 g (28%) of white crystals of 16.

Provenance & Evidence