HCID 23577305, compound → HCID 22135673, compound

HRID 1351598Notes

Reaction equation

HRID 1351598 reaction equation
[CH3:1][C:2]1[S:6][C:5](/[CH:7]=[CH:8]/[C:9]([O:11][C:12]([CH3:15])([CH3:14])[CH3:13])=[O:10])=[CH:4][CH:3]=1.[CH3:16]C1SC(C2CC2C(OCCCC)=O)=CC=1>>[CH3:1][C:2]1[S:6][C:5]([CH:7]2[CH2:16][CH:8]2[C:9]([O:11][C:12]([CH3:15])([CH3:14])[CH3:13])=[O:10])=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 23577305HCID 23577305, compoundHCID 86594694HCID 86594694, compound

Product 1

HCID 22135673HCID 22135673, compound

Procedure

tert-Butyl (2E)-3-(5-methylthien-2-yl)prop-2-enoate was cyclopropanated according to the procedure described for EXAMPLE 136, STEP 2, providing, after chromatography, ten-butyl 2-(5-methylthien-2-yl)cyclopropanecarboxylate.

Workup

  1. customproviding

Sources & evidence

ORD record
ord-a31578d8306445a18e8127edeae920c7
Source dataset
uspto-grants-2007_05
Patent number
US07217716B2

Reaction notes

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