HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 18007303, compound → 3-methoxy-6,7,8,9-tetrahydro-5H-benzo[7]annulen-6-amine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 18007303 | HCID 18007303 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | 3-methoxy-6,7,8,9-tetrahydro-5H-benzo[7]annulen-6-amine | HCID 18007320 | 105.9% |
Reaction Steps
A mixture of N-benzyl-(3-methoxy-6,7,8,9-tetrahydro-5H-benzocyclohepten-6-yl)amine (1.0 g) and 10% palladium on activated carbon (50% wet, 300 mg) in methanol (10 ml) was stirred at room temperature in the presence of hydrogen at an atmospheric pressure for 5.5 hours. After filtration, the filtrate was evaporated in vacuo to give 3-methoxy-(6,7,8,9-tetrahydro-5H-benzocyclohepten-6-yl)amine (720 mg).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07217706B2 |
| Source dataset | uspto-grants-2007_05 |
| ORD ID | ord-5e533309ae32416aa5704c0032165e9c |
| Source note | uspto-grants-2007_05 |