HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl 4-Formylbenzoate → HCID 21101171, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl 4-Formylbenzoate | HCID 15294 | — |
| Reactant | 4,5-Dichloro-1,2-phenylenediamine | HCID 79297 | — |
| Solvent | Nitrobenzene | HCID 7416 | — |
| Solvent | Hexane | HCID 8058 | — |
| Product | HCID 21101171 | HCID 21101171 | 68.9% |
Reaction Conditions
| Temperature | 140 °C |
|---|
Reaction Steps
A mixture of 4,5-dichlorophenylendiamine (4 g, 22.6 mmol) and methyl 4-formylbenzoate (3.68, 22.6 mmol) in nitrobenzene (35 ml) was heated at 140° C. for 30 h. After cooling, the mixture was diluted with n-hexane (150 ml) and stirred for 1 h. The solid was filtered obtaining 5 g of the title compound (yield 68.9%) as a brown powder, mp=240–250° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07220769B2 |
| Source dataset | uspto-grants-2007_05 |
| ORD ID | ord-66b44b69be36455fb0d68af7a91543ae |
| Source note | uspto-grants-2007_05 |