Glycerol → HCID 86588643, compound

HRID 1355305Notes

Reaction equation

HRID 1355305 reaction equation
[B:1]([OH:4])([OH:3])[OH:2].[OH:5][CH2:6][CH:7]([CH2:9][OH:10])[OH:8]>C1(C)C=CC=CC=1>[B:1]([OH:4])([OH:3])[OH:2].[OH:5][CH2:6][CH:7]([CH2:9][OH:10])[OH:8].[OH:5][CH2:6][CH:7]([CH2:9][OH:10])[OH:8]

Participants

4

Reactant 2

HCID 753GlycerolHCID 7628Boric Acid

Product 1

HCID 86588643HCID 86588643, compoundYield 73.4%

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

was prepared as follows. Boric acid (10.3 grams) and glycerol (30.6 grams) were added to a 250 milliliter flask. One hundred fifty milliliters of toluene was then added. The reaction was allowed to proceed overnight at 110° C., and the byproduct water (˜9 grams) was continuously removed from the reaction by azeotropic distillation. The final solution was evaporated to remove toluene under vacuum, and a viscous liquid product (˜30 grams) of diglycerol borate was obtained.

Workup

  1. customwas prepared
  2. customthe byproduct water (˜9 grams) was continuously removed from the reaction by azeotropic distillation
  3. customThe final solution was evaporated
  4. customto remove toluene under vacuum

Sources & evidence

ORD record
ord-e697096fac5d44bf8fb58f144e2c3723
Source dataset
uspto-grants-2003_07
Patent number
US06585816B1

Reaction notes

Loading…