HuagongsheHuagongshe Chemistry Print Report · For research reference only
m-Chloroperbenzoic acid → 2-(4-([1,1'-Biphenyl]-4-ylmethoxy)phenyl)-N-(2-(dimethylnitroryl)ethyl)acetamide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | m-Chloroperbenzoic acid | HCID 70297 | — |
| Reactant | 4-(4-Biphenylylmethoxy)phenyl-N-[2-(N,N-dimethylamino)ethyl]acetamide | HCID 9910268 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | 2-(4-([1,1'-Biphenyl]-4-ylmethoxy)phenyl)-N-(2-(dimethylnitroryl)ethyl)acetamide | HCID 18508348 | 48% |
Reaction Steps
To a solution of 2-(4-([1,1′-biphenyl]-4-ylmethoxy)phenyl)-N-(2-(dimethylamino)ethyl)acetamide (0.2 g) in acetone (30 ml) was added m-chloroperbenzoic acid (0.2 g) and stirring was continued at room temperature for 18 hr. The reaction mixture was concentrated. The residue was recrystallized twice from ethyl acetate to obtain the titled compound (0.1 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06586475B1 |
| Source dataset | uspto-grants-2003_07 |
| ORD ID | ord-d61fc2194543486083946f31dba3c706 |
| Source note | uspto-grants-2003_07 |