HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hexane → N-Cinnamyl-N-methyl-(3-isopropenylbenzyl)amine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hexane | HCID 8058 | — |
| Reactant | 3'-(N-Cinnamyl-N-methylaminomethyl)acetophenone | HCID 69936145 | — |
| Reactant | Butyllithium | HCID 178418339 | — |
| Catalyst | Methyltriphenyliphosphonium bromide | HCID 74505 | — |
| Product | N-Cinnamyl-N-methyl-(3-isopropenylbenzyl)amine | HCID 69933763 | 50.5% |
Reaction Steps
The procedure described in Example 2 was repeated, except that Compound 46 (0.42 g; 1.50 mmol), methyl triphenylphosphonium bromide (1.5 eq), and n-butyl lithium in n-hexane (1.68 M: 1.5 eq) were used, to thereby yield 0.21 g of the target compound (yield: 50.5%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06586633B1 |
| Source dataset | uspto-grants-2003_07 |
| ORD ID | ord-43b7370eaf3c4c33b1fc42b9c3b5417d |
| Source note | uspto-grants-2003_07 |