Stannous Chloride → HCID 70018205, compound

HRID 1357077Notes

Reaction equation

HRID 1357077 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([CH2:10][CH:11]([NH:17][C:18](=[O:27])[CH2:19][CH2:20][C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=2)[C:12]([O:14][CH2:15][CH3:16])=[O:13])[CH:7]=[CH:8][CH:9]=1)([O-])=O.[Sn](Cl)Cl>>[NH2:1][C:4]1[CH:5]=[C:6]([CH2:10][CH:11]([NH:17][C:18](=[O:27])[CH2:19][CH2:20][C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=2)[C:12]([O:14][CH2:15][CH3:16])=[O:13])[CH:7]=[CH:8][CH:9]=1

Participants

3

Reactant 2

HCID 24479Stannous ChlorideHCID 70017496HCID 70017496, compound

Product 1

HCID 70018205HCID 70018205, compound

Procedure

Corresponding to Example 3b, 3.0 g of (6a) were reduced using tin-(II) dichloride. A white solid was obtained (yield: 1.2 g).

Workup

  1. customA white solid was obtained (yield: 1.2 g)

Sources & evidence

ORD record
ord-e70ce8b33fe445f0ae87b16c4846ad56
Source dataset
uspto-grants-2003_07
Patent number
US06589972B2

Reaction notes

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