Stannous Chloride → HCID 70016318, compound

HRID 1357079Notes

Reaction equation

HRID 1357079 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([S:10]([NH:13][C:14]2[CH:15]=[C:16]([CH2:20][CH:21]([NH:27][C:28](=[O:37])[CH2:29][CH2:30][C:31]3[CH:36]=[CH:35][CH:34]=[CH:33][CH:32]=3)[C:22]([O:24][CH2:25][CH3:26])=[O:23])[CH:17]=[CH:18][CH:19]=2)(=[O:12])=[O:11])[CH:7]=[CH:8][CH:9]=1)([O-])=O.[Sn](Cl)Cl>>[NH2:1][C:4]1[CH:5]=[C:6]([S:10]([NH:13][C:14]2[CH:15]=[C:16]([CH2:20][CH:21]([NH:27][C:28](=[O:37])[CH2:29][CH2:30][C:31]3[CH:36]=[CH:35][CH:34]=[CH:33][CH:32]=3)[C:22]([O:24][CH2:25][CH3:26])=[O:23])[CH:17]=[CH:18][CH:19]=2)(=[O:11])=[O:12])[CH:7]=[CH:8][CH:9]=1

Participants

3

Reactant 2

HCID 24479Stannous ChlorideHCID 70018028HCID 70018028, compound

Product 1

HCID 70016318HCID 70016318, compound

Procedure

Corresponding to Example 3d, 1.53 g of (6c) were treated with tin-(II) chloride. A yellowish solid was obtained (yield: 1.1 g).

Workup

  1. customA yellowish solid was obtained (yield: 1.1 g)

Sources & evidence

ORD record
ord-0ea316e780314985a9425c9dab926200
Source dataset
uspto-grants-2003_07
Patent number
US06589972B2

Reaction notes

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