Stannous Chloride → HCID 86583802, compound
Reaction equation
[C:1]1([S:7]([NH:10][CH2:11][CH:12]([C:17]2[CH:22]=[CH:21][CH:20]=[C:19]([O:23][CH2:24][C:25]3[CH:30]=[CH:29][CH:28]=[C:27]([N+:31]([O-])=O)[CH:26]=3)[CH:18]=2)[C:13]([O:15][CH3:16])=[O:14])(=[O:9])=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Sn](Cl)Cl>>[NH2:31][C:27]1[CH:26]=[C:25]([CH:30]=[CH:29][CH:28]=1)[CH2:24][O:23][C:19]1[CH:18]=[C:17]([CH:12]([CH2:11][NH:10][S:7]([C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)(=[O:9])=[O:8])[C:13]([O:15][CH3:16])=[O:14])[CH:22]=[CH:21][CH:20]=1Participants
3
Procedure
Corresponding to Example 3d, 442 mg of (8e) were treated with tin-(II) chloride. A yellowish solid was obtained (yield: 387 mg).
Workup
- customA yellowish solid was obtained (yield: 387 mg)
Sources & evidence
- ORD record
- ord-8c23078c8a6c4312875263caabd5d266
- Source dataset
- uspto-grants-2003_07
- Patent number
- US06589972B2
Reaction notes
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