Ammonia → HCID 11378534, compound

HRID 1357747Notes

Reaction equation

HRID 1357747 reaction equation
CO[C:3]1[C:8]([CH3:10])([CH3:9])[CH2:7][CH2:6][C:5](=[O:11])[CH:4]=1.[NH3:12]>>[NH2:12][C:3]1[C:8]([CH3:10])([CH3:9])[CH2:7][CH2:6][C:5](=[O:11])[CH:4]=1

Participants

3

Reactant 2

HCID 222AmmoniaHCID 15738551HCID 15738551, compound

Product 1

HCID 11378534HCID 11378534, compound

Conditions

Temperature
100 °C

Procedure

3-Methoxy-4,4-dimethyl-2-cyclohexen-I -one in condensed anhydrous ammonia (50 mL) was heated at 100 ° C. (850 psi) for 34 hours. Ammonia was removed by evaporation, the residue dissolved in ethyl acetate (5 mL) and filtered through Florisil to provide 1,14 g of the title compound as a pale tan oil.

Workup

  1. customAmmonia was removed by evaporation
  2. dissolutionthe residue dissolved in ethyl acetate (5 mL)
  3. filtrationfiltered through Florisil

Sources & evidence

ORD record
ord-5a931979f1b746c59db3c88f140564ac
Source dataset
uspto-grants-2003_07
Patent number
US06593335B1

Reaction notes

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