Tributyltin azide → HCID 178482711, compound

HRID 1357810Notes

Reaction equation

HRID 1357810 reaction equation
[CH2:1]([N:8]([CH3:30])[C:9]1[CH:14]=[CH:13][C:12]([C:15]([CH3:26])([CH2:23][C:24]#[N:25])[C:16]([N:18]2[CH2:22][CH2:21][CH2:20][CH2:19]2)=[O:17])=[CH:11][C:10]=1[N+:27]([O-:29])=[O:28])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C([Sn]([N:44]=[N+:45]=[N-:46])(CCCC)CCCC)CCC>>[CH2:1]([N:8]([CH3:30])[C:9]1[CH:14]=[CH:13][C:12]([C:15]([CH3:26])([CH2:23][C:24]2[NH:46][N:45]=[N:44][N:25]=2)[C:16]([N:18]2[CH2:22][CH2:21][CH2:20][CH2:19]2)=[O:17])=[CH:11][C:10]=1[N+:27]([O-:29])=[O:28])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 4984872Tributyltin azideHCID 69987502HCID 69987502, compound

Product 1

HCID 178482711HCID 178482711, compound

Procedure

Prepared analogously to Example 4g from 2-[4-(N-benzyl-methylamino)-3-nitro-phenyl]-2-methyl-3-cyano-1-pyrrolidino-propan-1-one and tributyl tin azide.

Sources & evidence

ORD record
ord-109faf9ba1ad4e7d8903233155e6cd17
Source dataset
uspto-grants-2003_07
Patent number
US06593355B2

Reaction notes

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