1-Bromohexane → HCID 11732181, compound

HRID 1358062Notes

Reaction equation

HRID 1358062 reaction equation
[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[CH2:5][C:4]=2[CH:3]=1.Br[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]>>[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[C:5]([CH2:13][CH2:14][CH2:2][CH2:3][CH2:4][CH3:12])([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[C:4]=2[CH:3]=1

Participants

3

Reactant 2

HCID 81011-BromohexaneHCID 2519872,7-Dichlorofluorene

Product 1

HCID 11732181HCID 11732181, compoundYield 91%

Procedure

2,7-Dichloro-9,9-di(l-hexyl)fluorene was prepared from 2,7-dichlorofluorene and 1-bromohexane following the procedure of Example 1 as colorless crystals (recrystallized from hexane) in 91 percent yield; melting point 66° C. to 67° C. HPLC analysis showed that the sample was 99 percent or greater pure and the spectral data confirmed the title structure.

Workup

  1. customas colorless crystals (recrystallized from hexane) in 91 percent yield

Sources & evidence

ORD record
ord-adbe979421204758897b7f3233f77017
Source dataset
uspto-grants-2003_07
Patent number
US06593450B2

Reaction notes

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