Potassium ethanethioate → HCID 86585314, 화합물

HRID 1358877노트

반응식

I[CH2:2][CH2:3][CH2:4][CH2:5][O:6][C:7]1[CH:12]=[CH:11][C:10]([C@H:13]2[CH2:30][C@@:28]3([CH3:29])[C@@H:24]([CH2:25][CH2:26][C@@H:27]3[OH:31])[C@H:23]3[C@H:14]2[C:15]2[CH:16]=[CH:17][C:18]([OH:32])=[CH:19][C:20]=2[CH2:21][CH2:22]3)=[CH:9][CH:8]=1.[C:33]([O-])(=[S:35])[CH3:34].[K+]>>[C:33]([CH2:2][CH2:3][CH2:4][CH2:5][O:6][C:7]1[CH:12]=[CH:11][C:10]([C@H:13]2[CH2:30][C@@:28]3([CH3:29])[C@@H:24]([CH2:25][CH2:26][C@@H:27]3[OH:31])[C@H:23]3[C@H:14]2[C:15]2[CH:16]=[CH:17][C:18]([OH:32])=[CH:19][C:20]=2[CH2:21][CH2:22]3)=[CH:9][CH:8]=1)(=[S:35])[CH3:34]

참가 물질

반응물 2

HCID 23670855Potassium ethanethioate

HCID 70019444HCID 70019444, 화합물

생성물 1

HCID 86585314HCID 86585314, 화합물수율 82.2%

실험 절차

The operation is carried out as in Stage E of Example 8 starting with 1.18 g of the product obtained in Stage D and 460 mg of potassium thioacetate. 850 mg of expected product is obtained. M.p. #90° C.

출처 및 근거

ORD 기록: ord-e8b67195ab4443d5b2587ec2cea8df40
출처 데이터셋: uspto-grants-2003_07
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06596885B2

반응 노트

불러오는 중…