HCID 10103995, compound → 3-BENZOYLTHIOPHENE

HRID 1359409Notes

Reaction equation

HRID 1359409 reaction equation
[C:1]1([CH:7]([C:9]2[CH:13]=[CH:12][S:11][CH:10]=2)[OH:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1>C(Cl)(Cl)Cl.[O-2].[O-2].[Mn+4]>[C:7]([C:9]1[CH:13]=[CH:12][S:11][CH:10]=1)(=[O:8])[C:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

4

Reactant 1

HCID 10103995HCID 10103995, compound

Product 1

HCID 2486473-BENZOYLTHIOPHENEYield 99.1%

Reagents, catalysts & solvents 2

HCID 178418406HCID 178418406, compoundCatalystHCID 6212ChloroformSolvent

Procedure

6.2 g of 1-phenyl-l-(3-thienyl)methanol was dissolved in 50 ml of chloroform. To the mixture was added 30 g of manganese dioxide, followed by stirring overnight. Manganese dioxide was filtered off, and the filtrate was evaporated, to give 6.08 g of the target compound.

Workup

  1. filtrationManganese dioxide was filtered off
  2. customthe filtrate was evaporated

Sources & evidence

ORD record
ord-de4d613b1639425dbd7df04fb0abf725
Source dataset
uspto-grants-2003_07
Patent number
US06599917B1

Reaction notes

Loading…