Triethylamine → HCID 66923969, compound

Participants

Reaction Steps

4-(Adamantan-1-ylamino)-1H-pyrrolo[2,3-b]pyridine-5-carboxylic acid (17 mg) and triethylamine (15 μl) were dissolved in dioxane (0.5 ml). To the mixture was added diphenylphosphoryl azide (DPPA) (18 μl) at 120° C. under stirring. The mixture was stirred at the same temperature for 2 hours and cooled to ambient temperature. The obtained solid was collected by filtration and washed with acetonitrile to obtain (adamantan-1-yl)-3,6-dihydroimidazo[4,5-d]pyrrolo[2,3-b]pyridine-2(1H)-one (11 mg).

Provenance & Evidence