HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-(Ethoxymethylene)propanedinitrile → 1H-Benzimidazole-6-carbonitrile
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-(Ethoxymethylene)propanedinitrile | HCID 67152 | — |
| Reactant | 3,4-Diaminobenzonitrile | HCID 737285 | — |
| Solvent | Isopropanol | HCID 3776 | — |
| Product | 1H-Benzimidazole-6-carbonitrile | HCID 223906 | — |
Reaction Steps
A mixture of 3,4-diaminobenzonitrile (2) (1.0 g) and (ethoxymethylene)malononitrile (1.4 g) was refluxed in 50 mL of isopropyl alcohol for 16 h. The mixture was concentrated in vacuo to provide the title compound, 3H-benzo[d]imidazole-5-carbonitrile (3).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07884109B2 |
| Source dataset | uspto-grants-2011_02 |
| ORD ID | ord-d9aadab0f5414477931c8f7a1a189282 |
| Source note | uspto-grants-2011_02 |