HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hexane → 2-Pentylcyclohexa-2,5-diene-1,4-dione
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hexane | HCID 8058 | — |
| Reactant | Ethyl Acetate | HCID 8857 | — |
| Reactant | 2-Pentylbenzene-1,4-diol | HCID 15757573 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | 2-Pentylcyclohexa-2,5-diene-1,4-dione | HCID 15757574 | 59% |
Reaction Steps
To the solution of 360 mg (2 mmol) of 21 in methanol, 650 mg (2 eq) of FeCl3 was added. The reaction mixture was stirred for 1 hr, and the solvent was removed. Silicagel chromatography (hexane: EA=20:1) gave 210 mg (59% yield) 22 as a brown solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07888055B2 |
| Source dataset | uspto-grants-2011_02 |
| ORD ID | ord-e32effb717e54d7097d0ad9b8a24d596 |
| Source note | uspto-grants-2011_02 |