Bromine → HCID 66932739, compound

HRID 1364083Notes

Reaction equation

HRID 1364083 reaction equation
[CH2:1]([CH:4]1[CH2:9][C:8](=[O:10])[CH2:7][C:6](=[O:11])[CH2:5]1)[CH2:2][CH3:3].[Br:12]Br>CC(O)=O>[Br:12][CH:7]1[C:6](=[O:11])[CH2:5][CH:4]([CH2:1][CH2:2][CH3:3])[CH2:9][C:8]1=[O:10]

Participants

4

Reactant 2

HCID 24408BromineHCID 27372245-Propylcyclohexane-1,3-dione

Product 1

HCID 66932739HCID 66932739, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

To a stirred solution of 5-propylcyclohexane-1,3-dione (1.54 g, 10 mmol) in AcOH (20 mL) at r.t. was added bromine (1.6 g, 0.51 mL, 1 mmol) dropwise. The reaction was carried out according to Method A to give the title compound in quantitative yield as a light brown solid, which was used without further purification. LCMS (ES+) 232.9 (M+H)+.

Sources & evidence

ORD record
ord-687624488a8f4edb854d5765897a87a7
Source dataset
uspto-grants-2011_02
Patent number
US07888344B2

Reaction notes

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