Bromine → HCID 66932694, compound

HRID 1364084Notes

Reaction equation

HRID 1364084 reaction equation
[C:1]1([CH:7]2[CH2:12][C:11](=[O:13])[CH2:10][C:9](=[O:14])[CH2:8]2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Br:15]Br>CC(O)=O>[Br:15][CH:10]1[C:9](=[O:14])[CH2:8][CH:7]([C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)[CH2:12][C:11]1=[O:13]

Participants

4

Reactant 2

HCID 24408BromineHCID 5689621,3-Cyclohexanedione, 5-phenyl-

Product 1

HCID 66932694HCID 66932694, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

To a stirred solution of 5-phenylcyclohexane-1,3-dione (1.88 g, 10 mmol) in AcOH (20 mL) at r.t. was added bromine (1.6 g, 0.51 mL, 10 mmol) dropwise. The reaction was carried out according to Method A to give the title compound in quantitative yield as a light brown solid, which was used without further purification. LCMS (ES+) 266.8 (M+H)+.

Sources & evidence

ORD record
ord-45804dbba4ea4071b737614f700f54a9
Source dataset
uspto-grants-2011_02
Patent number
US07888344B2

Reaction notes

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